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Modified Alpha-Beta Chimeric Oligodna as a Unique Class of Tfo

Modified Alpha-Beta Chimeric Oligodna as a Unique Class of Tfo

Modified Alpha-Beta Chimeric Oligodna as a Unique Class of Tfo.cA T M Zafrul Azam
Modified Alpha-Beta Chimeric Oligodna as a Unique Class of Tfo
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Author: A T M Zafrul Azam
Page Count: 160 pages
Published Date: 18 Oct 2011
Publisher: LAP Lambert Academic Publishing
Publication Country: Germany
Language: English
Format: PDF
ISBN: 9783846532461
Download Link: modified alpha-beta chimeric oligodna as a unique class of tfo
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A series of novel alpha-beta chimeric oligodeoxynucleotides bearing either an intercalator-conjugated nucleobase located at the internal 4-nt linker region or an anthraquinone-conjugated propionic acid as a non-nucleosidic backbone unit at the internal linker region was synthesized. The UV-melting experiments reveled that the obtained modified chimera TFOs formed remarkably stable alternate-stranded triplex. On the other hand, modified TFOs bearing non-nucleosidic intercalator-conjugate possessed two diastereomers formed substantially stable alternate-stranded triple helix almost regardless of the stereochemistry of the incorporated non-nucleosidic backbone unit. The sequence discrimination ability and thermodynamic stability of some TFOs were also examined.

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